Morphologic variability of exposed mass-transport deposits on the eastern slope of Gela Basin (Sicily channel)

The NE portion of Gela Basin in the Sicily Channel is affected by multiple slope failures originated during the late‐Quaternary. Basin sequences show evidence of stacked acoustically transparent and/or chaotic units, characterized by irregular upper surfaces, interpreted as mass‐transport deposits. The seafloor morphology also shows evidence of both old, partially buried, as well as recent slide products. Two recent slides exposed at seafloor, only 6 km apart (Twin Slides), are similar in geomorphological parameters, age and multistage evolution. Multistage failure of Twin Slides evolved from mud flows, derived from the extensive failure of less consolidated post‐glacial units, to localized slides (second stage of failure) affecting older and more consolidated materials. Although Twin Slides are very close to each other and have similar runout and fall height, they produced very dissimilar organization of the displaced masses, likely reflecting the distinct source units affected by failures. Integrating geophysical, sedimentological, structural and palaeontological data, a detailed investigation was conducted to determine the size and internal geometry of this mass‐transport complex, to explain the differentiated product and to shed light on its predisposing factors, triggers and timing.     

Converted-wave imaging in anisotropic media: theory and case studies

Common‐conversion‐point binning associated with converted‐wave (C‐wave) processing complicates the task of parameter estimation, especially in anisotropic media. To overcome this problem, we derive new expressions for converted‐wave prestack time migration (PSTM) in anisotropic media and illustrate their applications using both 2D and 3D data examples. The converted‐wave kinematic response in inhomogeneous media with vertical transverse isotropy is separated into two parts: the response in horizontally layered vertical transverse isotrophy media and the response from a point‐scatterer. The former controls the stacking process and the latter controls the process of PSTM. The C‐wave traveltime in horizontally layered vertical transverse isotrophy media is determined by four parameters: the C‐wave stacking velocity V_C2, the vertical and effective velocity ratios γ₀ and γ_eff, and the C‐wave anisotropic parameter χ_eff. These four parameters are referred to as the C‐wave stacking velocity model. In contrast, the C‐wave diffraction time from a point‐scatterer is determined by five parameters: γ₀, V_P2, V_S2, η_eff and ζ_eff, where η_eff and ζ_eff are, respectively, the P‐ and S‐wave anisotropic parameters, and V_P2 and V_S2 are the corresponding stacking velocities. V_P2, V_S2, η_eff and ζ_eff are referred to as the C‐wave PSTM velocity model. There is a one‐to‐one analytical link between the stacking velocity model and the PSTM velocity model. There is also a simple analytical link between the C‐wave stacking velocities V_C2 and the migration velocity V_Cmig, which is in turn linked to V_P2 and V_S2. Based on the above, we have developed an interactive processing scheme to build the stacking and PSTM velocity models and to perform 2D and 3D C‐wave anisotropic PSTM. Real data applications show that the PSTM scheme substantially improves the quality of C‐wave imaging compared with the dip‐moveout scheme, and these improvements have been confirmed by drilling.     

Performance of a base isolator with shape memory alloy bars

A new and innovative base isolation device is introduced in this paper based on extensive research carried out by the authors and their co-workers. A prototype of the device was built and experimentally tested on the shaking table. The new base isolation device consists of two disks, one vertical cylinder with an upper enlargement sustained by three horizontal cantilevers, and at least three inclined shape memory alloy (SMA) bars. The role of the SMA bars is to limit the relative motion between the base and the superstructure, to dissipate energy by their super-elastic constitutive law and to guarantee the re-centring of the device. To verify the expected performance, a prototype was built and tested under sinusoidal waves of displacement of increasing frequency with different amplitudes. It is shown that the main feature of the proposed base isolation device is that for cyclic loading, the super-elastic behavior of the alloy results in wide load-displacement loops, where a large amount of energy is dissipated.     

Realistic Modeling of Seismic Input in Urban Areas: A UNESCO-IUGS-IGCP Project

—?The estimation of realistic seismic input can be obtained from the computation of a wide set of time histories and spectral information, corresponding to possible seismotectonic scenarios for different source and structural models. Such a data set can be very constructively used by civil engineers in the design of new seismo-resistant structures and in the reinforcement of the existing built environment, therefore supplying a particularly powerful tool to the prevention efforts of Civil Defense. The availability of realistic numerical simulations enables us to estimate the amplification effects in complex geological structures exploiting the available geotechnical, lithological, geophysical parameters, topography of the medium, tectonic, historical, paleoseismological data, and seismotectonic models. The realistic modeling of the ground motion is a very important source of knowledge for the preparation of groundshaking scenarios which represent a valid and economical tool in seismic microzonation.     

An EPR and SQUID magnetometry study of bornite

A magnetic and spectroscopic characterisation has been performed on a natural bornite sample from the Natural History Museum of the University of Florence. The combination of magnetic measurements and continuous-wave electron paramagnetic resonance (cw-EPR) spectroscopy at different temperatures and frequencies provided information about the distribution and valence states of Cu and Fe in bornite. The studied sample was found to obey the Curie–Weiss law with a transition from a paramagnetic to an antiferromagnetic phase at 64 K; its possible attribution to a disordered spin glass phase was ruled out by ac susceptibility measurements. Q- and X-band cw-EPR measurements confirmed the presence of Fe(III) as fundamental valence state in bornite: the single EPR line registered in the temperature range from 300 to 65 K can be assigned, in fact, to the Fe(III) single ions. Some Cu(II) signals were revealed in the low temperature EPR spectra and attributed to an early stage of the surface alteration. The width of the Fe(III) EPR spectrum, which hinders any characteristic spectral structure, can be ascribed to the exchange interaction. The pure antiferromagnetic character of the magnetic transition confirms the ordering between Fe and Cu in the bornite structure, at least at low temperature (≤70 K). Moreover, the relatively high Nèel temperature suggests the accepted model of Collins et al.’s (Can J Phys 59:535–539, 1981) to conveniently explain the overall magnetic properties in the range 298–4 K. Despite the increasing of the susceptibility in the paramagnetic range, in fact, the integrated EPR line area decreases by lowering the temperature, thus suggesting a progressive rising of the antiferromagnetic interactions among next-nearest-neighbouring paramagnetic centres.     

POLARIX: a pathfinder mission of X-ray polarimetry

Since the birth of X-ray astronomy, spectral, spatial and timing observation improved dramatically, procuring a wealth of information on the majority of the classes of the celestial sources. Polarimetry, instead, remained basically unprobed. X-ray polarimetry promises to provide additional information procuring two new observable quantities, the degree and the angle of polarization. Polarization from celestial X-ray sources may derive from emission mechanisms themselves such as cyclotron, synchrotron and non-thermal bremsstrahlung, from scattering in aspheric accreting plasmas, such as disks, blobs and columns and from the presence of extreme magnetic field by means of vacuum polarization and birefringence. Matter in strong gravity fields and Quantum Gravity effects can be studied by X-ray polarimetry, too. POLARIX is a mission dedicated to X-ray polarimetry. It exploits the polarimetric response of a Gas Pixel Detector, combined with position sensitivity, that, at the focus of a telescope, results in a huge increase of sensitivity. The heart of the detector is an Application-Specific Integrated Circuit (ASIC) chip with 105,600 pixels each one containing a full complete electronic chain to image the track produced by the photoelectron. Three Gas Pixel Detectors are coupled with three X-ray optics which are the heritage of JET-X mission. A filter wheel hosting calibration sources unpolarized and polarized is dedicated to each detector for periodic on-ground and in-flight calibration. POLARIX will measure time resolved X-ray polarization with an angular resolution of about 20 arcsec in a field of view of 15 × 15 arcmin and with an energy resolution of 20% at 6 keV. The Minimum Detectable Polarization is 12% for a source having a flux of 1 mCrab and 10⁵ s of observing time. The satellite will be placed in an equatorial orbit of 505 km of altitude by a Vega launcher. The telemetry down-link station will be Malindi. The pointing of POLARIX satellite will be gyroless and it will perform a double pointing during the earth occultation of one source, so maximizing the scientific return. POLARIX data are for 75% open to the community while 25% + SVP (Science Verification Phase, 1 month of operation) is dedicated to a core program activity open to the contribution of associated scientists. The planned duration of the mission is one year plus three months of commissioning and SVP, suitable to perform most of the basic science within the reach of this instrument. A nice to have idea is to use the same existing mandrels to build two additional telescopes of iridium with carbon coating plus two more detectors. The effective area in this case would be almost doubled.     

A Fe K-edge XAS study of amethyst

An X-ray absorption spectroscopy (XAS) study of the Fe local environment in natural amethyst (a variety of α-quartz, SiO₂) has been carried out. Room temperature measurements were performed at the Fe K-edge (7,112 eV), at both the X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) regions. Experimental results were then compared with DFT calculations. XANES experimental spectra suggest Fe to occur mainly in the trivalent state, although a fraction of Fe²⁺ is identified. EXAFS spectra, on the other hand, reveal an unusual short distance for the first coordination shell:  = 1.78(2) Å, the coordination number being 2.7(5). These results allow to establish that Fe replaces Si in its tetrahedral site, and that numerous local distortions are occurring as a consequence of the presence of Fe³⁺ variably compensated by protons and/or alkaline ions, or uncompensated. The formal valence of Fe, on the basis of both experimental and DFT structural features, can be either 4+ or 3+. Taking into account the XANES evidences, we suggest that Fe mainly occurs in the trivalent state, compensated by protons, and that a minor fraction of Fe⁴⁺ is stabilised by the favourable local structural arrangement.     

Olive tree phenology and climate variations in the Mediterranean area over the last two decades

The flowering characteristics of plant species of economic interest and the influence of climate on them are of great importance considering the implications for fruit setting and the final harvest: Olive is one of the typical species of the Mediterranean habitat. We have investigated the timing of olive full flowering during the anthesis period and flowering intensity over a period of 20 years (1990–2009), in three major cultivation areas of the Mediterranean basin: Italy, Spain and Tunisia. The importance of these characteristics from a bioclimatic point of view is considered. The biological behaviour was studied to determine its main relationships with temperature and water availability, considering also the different sub-periods and the bio-climatic variations during the study period. The flowering dates and pollen emissions show different behaviours for the Spanish monitoring area in comparison with the other two olive cultivation areas. In the Italian and Tunisian areas, the flowering period over the last decade has become earlier by about 5 and 7 days, respectively, in comparison to the previous decade. Moreover, pollen emissions have decreased in Perugia (Italy) and Zarzis (Tunisia) over the period of 2000–2009, while in Cordoba (Spain), they showed their highest values from 2005 to 2009. The climate analysis has shown an increase in temperature, which results in an increase in the growing degree days for the growth of the olive flower structures, particularly in the more northern areas monitored. Although the olive tree is a parsimonious water consumer that is well adapted to xeric conditions, the increase in the potential evapotranspiration index over the last decade in the Italian and Tunisian olive areas might create problems for olive groves without irrigation, with a negative influence on the flowering intensity. Overall, in all of these Mediterranean monitoring areas, the summer water deficit is an increasingly more important parameter in comparison to the winter parameters, which confirms that the winter period is not as limiting as the summer period for olive tree cultivation in these Mediterranean areas.     

Human alteration of groundwater–surface water interactions (Sagittario River,Central Italy): implication for flow regime,contaminant fate and invertebrate response

Many rivers worldwide are undergoing severe man-induced alterations which are reflected also in changes of the degree of connectivity between surface waters and groundwater. Pollution, irrigation withdrawal, alteration of freshwater flows, road construction, surface water diversion, soil erosion in agriculture, deforestation and dam building have led to some irreversible species losses and severe changes in community composition of freshwater ecosystems. Taking into account the impact of damming and flow diversion on natural river discharge, the present study is aimed at (i) evaluating the effects of anthropogenic changes on groundwater/surface water interactions; (ii) analyzing the fate of nitrogenous pollutants at the floodplain scale; and (iii) describing the overall response of invertebrate assemblages to such changes. Hydrogeological, geochemical and isotopic data revealed short- and long-term changes in hydrology, allowing the assessment of the hydrogeological setting and the evaluation of potential contamination by nitrogen compounds. Water isotopes allowed distinguishing a shallow aquifer locally fed by zenithal recharge and river losses, and a deeper aquifer/aquitard system fed by surrounding carbonate aquifers. This system was found to retain ammonium and, through the shallow aquifer, release it in surface running waters via the hyporheic zone of the riverbed. All these factors influence river ecosystem health. As many environmental drivers entered in action offering a multiple-component artificial environment, a clear relationship between river flow alteration and benthic and hyporheic invertebrate diversity was not found, being species response driven by the combination of three main stressors: ammonium pollution, man-induced changes in river morphology and altered discharge regime.